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Beilstein J. Org. Chem. 2012, 8, 155–163, doi:10.3762/bjoc.8.16
Graphical Abstract
Figure 1: Chemical structure of the helical perylenequinones under investigation: Cercosporin (1) and phleich...
Figure 2: Newman projections of the conformational states of the side chain linked at C1 of cercosporin (1), ...
Figure 3: “Propeller” (left) and “double butterfly” geometry (right) of the g+ g+ conformer of 1, as obtained...
Figure 4: Optimized geometry of all conformers of 1 (upper half) and 2 (lower half), obtained at the DFT/M06-...
Figure 5: Chirality parameter Q (diamonds) and probability distribution (bars), calculated for all conformers...